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KMID : 1059519980420050512
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Journal of the Korean Chemical Society
1998 Volume.42 No. 5 p.512 ~ p.518
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Characterization and Solution Behavior of Polyethylene-based Ionomer Particles in Water
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Yeo Sang-Ihn
Woo Kyu-Whan
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Abstract
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In this study, various thermodynamic and hydrodynamic parameters characterizing the solution properties of polyethylene ionomer particles in water were determined at 30℃ by means of light scattering and viscosity measurements. Based on the experimental data, we investigated the solution behavior of three kinds of polyethylene ionomers, which are different in composition of the pendant ionic groups of COOK, COOH and CONH2, and characterized their particle properties. Ionomers containing 7.6 mol% potassium salt only behave as flexible coils in a relatively good solvent state. On the other hand, two ionomers containing 3.8 mol% amide group together with potassium salt form the compact particles. In addition, the concentration dependence of the effective diffusion coefficient (Deff) and the reduced viscosity of the latter ionomers showed the opposite trend from the former, indicating that the composition of the pendant ionic groups have a great influence on the interparticle interaction of ionomers formed in water.
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